Please use this identifier to cite or link to this item:
Title: Rutile Nanorods: Synthesis, Structure And Electrochemical Properties
Authors: Kotsyubynsky, V.
Myronyuk, I.
Chelyadyn, V.
Moklyak, V.
Keywords: crystal structure
lithium intercalation
impedance spectroscopy
Issue Date: 2014
Publisher: Vasyl Stefanyk Precarpathian National University
Citation: Kotsyubynsky V. O. Rutile Nanorods: Synthesis, Structure And Electrochemical Properties / V. O. Kotsyubynsky, I. F. Myronyuk, V. L. Chelyadyn, V. V. Moklyak // Journal of Vasyl Stefanyk Precarpathian National University. - 2014. - Vol. 1. - № 1. - P. 27-32.
Abstract: Nanodispersed rutile with rod-like particles was synthesized by hydrolysis of TiCl4 in hydrochloric acid - ethanol alcohol aqueous solution at 40°C. It was found that the specific surface area, crystallite size, degree of agglomeration are determined by molar ratios of ethanol. The obtained material was used as the base of cathode composition for lithium power sources. The maximum values of specific capacity (250 mAh/g) at discharge in galvanostatic conditions are fixed in the case of using material with the maximum agglomeration degree and minimal particle size. Phasic character of Li+ ions intercalation is set and the diffusion coefficient at different stages of the process is calculated.
Appears in Collections:Vol. 1, № 1

Files in This Item:
File Description SizeFormat 
255-1019-1-PB.pdf944.07 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.